/usr/share/doc/avogadro/examples/acid_chlorides.smi is in avogadro 1.2.0-1+deb9u1.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
1 2 3 | CC(=O)Cl acetyl chloride
CCC(=O)Cl propanoyl chloride
c1ccccc1C(=O)Cl benzoyl chloride
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