/etc/schroot/schroot.conf is in schroot 1.6.10-4build1.
This file is owned by root:root, with mode 0o644.
The actual contents of the file can be viewed below.
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# See schroot.conf(5) for complete documentation of the file format.
#
# Please take note that you should not add untrusted users to
# root-groups, because they will essentially have full root access
# to your system. They will only have root access inside the chroot,
# but that's enough to cause malicious damage.
#
# The following lines are examples only. Uncomment and alter them to
# customise schroot for your needs, or create a new entry from scratch.
#
#
#[sid]
#description=Debian sid (unstable)
#directory=/srv/chroot/sid
#users=rleigh
#groups=sbuild
#root-groups=root
#aliases=unstable,default
#
#[sid-snap]
#type=lvm-snapshot
#description=Debian sid LVM snapshot
#groups=sbuild,root
#root-users=rleigh
#root-groups=root,sbuild
#source-root-users=rleigh
#device=/dev/hda_vg/sid_chroot
#mount-options=-o atime,sync,user_xattr
#lvm-snapshot-options=--size 2G
#
#[sid-bsnap]
#type=btrfs-snapshot
#description=Debian sid btrfs snapshot
#btrfs-source-subvolume=/srv/chroot/btrsnap/sid-snap
#btrfs-snapshot-directory=/srv/chroot/btrsnap/snapshots
#groups=root,sbuild
#root-groups=root,sbuild
#
#[squeeze]
#description=Debian squeeze (stable) 32-bit
#directory=/srv/chroot/squeeze
#groups=sbuild-security
#aliases=stable
#personality=linux32
#
#[lenny]
#description=Debian lenny (oldstable)
#directory=/srv/chroot/lenny
#groups=sbuild
#aliases=oldstable
#
#[lenny-file]
#description=Debian lenny (oldstable)
#file=/srv/chroot/lenny.tar.gz
#location=/lenny
#groups=sbuild
#
#[lenny-secure]
#description=Debian lenny (oldstable)
#directory=/srv/chroot/lenny
#groups=sbuild-security
#aliases=stable-security
#
#[experimental]
#type=block-device
#description=Debian experimental
#groups=sbuild,root
#root-groups=root,sbuild
#device=/dev/hda_vg/experimental_chroot
#mount-options=-o atime,sync,user_xattr
#location=/experimental
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