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#! cc3: RHF-CCSD/6-31G** H2O geometry optimization and vibrational frequency
#! analysis by finite-differences of gradients

molecule h2o {
  0 1
  O 
  H 1 0.97
  H 1 0.97 2 103.0
}

set {
  basis 6-31G**
  r_convergence 10
  e_convergence 10
}

optimize('ccsd')

refnuc   =  9.166137300098260  #TEST
refscf   = -76.02293995043653  #TEST
refccsd  = -0.208238532935749  #TEST
reftotal = -76.2311784833722   #TEST

compare_values(refnuc,   h2o.nuclear_repulsion_energy(),          3, "Nuclear repulsion energy") #TEST
compare_values(refscf,   get_variable("SCF total energy"),        5, "SCF energy")               #TEST
compare_values(refccsd,  get_variable("CCSD correlation energy"), 4, "CCSD contribution")        #TEST
compare_values(reftotal, get_variable("Current energy"),          7, "Total energy")             #TEST

ccsd_e, ccsd_wfn = frequencies('ccsd', dertype=1, return_wfn=True)
fd_freqs_grad = ccsd_wfn.frequencies()

ccsd_e, ccsd_wfn, frequencies('ccsd', dertype=0, return_wfn=True)
fd_freqs_energy = ccsd_wfn.frequencies()

compare_vectors(fd_freqs_grad, fd_freqs_energy, 1, "CCSD Grads vs. Energies Findif (3-pt.) freqs to 0.1 cm^-1")  #TEST